Photocatalytic methane activation by dual reaction sites co-modified WO3
نویسندگان
چکیده
Methane (CH4) upgrading into liquid oxygenates under mild conditions is of great significance to sustainable energy and clean environment, whilst holds challenges achieving superior activity selectivity. Herein, tungsten oxide (WO3) modified with palladium (Pd) nanoparticles oxygen vacancies (OVs) was employed as dual reaction sites drive CH4 conversion O2 at room temperature. Optimized Pd0.5-def-WO3 photocatalyst enables almost 33 times improvement in production compared WO3, a yield 7018 ?mol·g–1·h–1, high selectivity 81% towards primary products (CH3OH CH3OOH), which most the previous reported. In-situ XPS spectra proved Pd were hole acceptors based on shift Pd3d binding light irradiation. The in-situ solid-state EPR demonstrate an enhancement OVs signal proves role electron acceptors. Consequently, efficient charge separation has been achieved, contributing for conversion.
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ژورنال
عنوان ژورنال: Chinese Journal of Catalysis
سال: 2023
ISSN: ['0253-9837', '1872-2067']
DOI: https://doi.org/10.1016/s1872-2067(22)64169-x